Jurgen F. Stilck, Physics Institute, Fluminense Federal University, Niteroi, RJ, Brazil.
Event Date:
Monday, 18 January 2016 - 2:30pm to 3:30pm
Title: The nature of the polymer collapse transition Abstract: In a good solvent, a polymer chain assumes an extended configuration. Asthe solvent quality (or the temperature) is lowered, the configuration
changes to globular, which is more compact. This collapse transition is
also called coil-globule transition in the literature. Since the pioneering
work by de Gennes, it is known that it corresponds to a tricritical point
in a grand-canonical parameter space. In the most used lattice model to
study it, the chain is represented by a self-avoiding walk on the lattice
and the solvent is effectively taken into account by including attractive
interactions between monomers on first neighbor sites which are not
consecutive along a chain (SASAW's: self-attracting self-avoiding walks).
We will review the model and show that small changes in it may lead to
different phase diagrams, where the collapse transition is no longer a
tricritial point. In particular, if the polymer is represented by a trail,
which allows for multiple visits of sites but mantains the constraint of
single visits of edges, we find two distinct polymerized phases besides the
non-polymerized phase and the collapse transition becomes a bicritical
point.
Venue:
Departmental Library, Physics Department (second floor)
IIT Bombay, Powai, Mumbai